The U-value tells you how much heat escapes through one square metre of the wall, the roof or the floor. The lower the number, the better it insulates. Choose your construction and see the answer straight away. If you are converting or extending, step 5 shows what the building regulations require.
On a conversion, energy savings must be carried out when they are profitable and do not create a risk of moisture damage (BR18 s. 274). They are profitable when annual saving × lifetime ÷ investment is above 1.33 (s. 275). The calculation here uses the construction you put together above — that becomes the "after", and you state what it looks like today.
An extension can be documented in three ways (BR18 s. 271): with the energy frame, with the U-values in table 2 and no more than 22 % windows — or with the heat loss frame in s. 272. Enter the dimensions of the extension and you see which routes hold. The building element you calculated above goes in with its own U-value.